If your use of this as a diagnostic is new/different and unexpected you may have a chance of getting it approved as a new patent.
However, just because you have a patent approved does not mean you are "free and clear" to start making that device. The original patent holder may be able to stop you from making or selling the device even if you found a new use for it.
For example, I cannot sell iPhones as paperweights (even if I was the first person to think of that idea) without violating at least one of Apples 1000s of patents on the iPhone.